MEAN ACTIVITY-COEFFICIENTS IN THE TERNARY NACL-NANO3-H2O AND NABR-NANO3-H2O SYSTEMS AT 298.15-K

被引：53

作者：

HAGHTALAB, A ^{[1
]}

VERA, JH ^{[1
]}

机构：

[1] MCGILL UNIV,DEPT CHEM ENGN,MONTREAL H3A 2A7,QUEBEC,CANADA

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1991年 / 36卷 / 03期

关键词：

D O I：

10.1021/je00003a022

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The mean activity coefficients of NaCl in the NaCl-NaNO3-H2O system and NaBr in the NaBr-NaNO3-H2O system have been measured at 298.15 K over the range of ionic strengths from 0.3 to 6 m. The measurements were made by an electrochemical cell using ion-selective electrodes (ISE). The data were collected with an Orion millivolt (mV) meter, Model EA 920, using Na-ISE against Cl-ISE and Br-ISE as reference electrodes. The experimental mean activity coefficients of NaCl and NaBr obey Harned's Rule. The mean activity coefficients of NaNO3 were calculated by using the Gibbs-Duhem equation.

引用

页码：332 / 340

页数：9

共 50 条

[31] Activity Coefficient Measurements in the Ternary System NaNO3-Cu(NO3)2-H2O at 298.15 K by the Cell Potential Method [J].

Sang, Shi-Hua ;

Wei, Xue-Qi ;

Ma, Xu-Chun ;

Gao, Yun-Yun ;

Lei, Ning-Fei ;

Cui, Rui-Zhi .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2021, 66 (03) :1255-1263

[32] Mean Ionic Activity Coefficients of NaBr in the Ternary System NaBr-SrBr2-H2O at 288.15 K using the Cell Potential Method [J].

Liu, Xing ;

Zhao, Lan-Rong ;

Sang, Shi-Hua ;

Gao, Yun-Yun ;

Ge, Qi .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2020, 65 (11) :5083-5089

[33] Activity coefficients in quaternary electrolytic systems: NaCl + NaFormate + NaAcetate + H2O, NaCl + NaFormate + NaPropionate + H2O and NaBr + NaFormate + NaAcetate + H2O [J].

Fluid Phase Equilib, 1 (139-156)

[34] Mean Activity Coefficients for NaCl in the Mixtures Containing Ionic Liquids [Emim][MeSO3] + H2O and [Emim][EtSO4] + H2O at 298.15 K [J].

Amado-Gonzalez, Eliseo ;

Esteso, Miguel A. ;

Gomez-Jaramillo, Wilfred .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2017, 62 (02) :752-761

[35] Measurements and Calculations mean activity coefficients of KI in the KI-KCl-H2O ternary system at 298.15 K [J].

Wang, Wei ;

Sang, Shi-Hua ;

Ren, Hong-Bao ;

Zheng, Lin ;

Pan, Jin-Gong .

JOURNAL OF MOLECULAR LIQUIDS, 2022, 346

[36] POLITERMA TROINOI SISTEMY NANO3-NACL-H2O [J].

KHITROVA, NN .

ZHURNAL PRIKLADNOI KHIMII, 1954, 27 (12) :1281-1289

[37] Thermodynamic Study of the NaNO3-Cd(NO3)2-H2O Ternary System at 298.15 K by the Potential Difference Method [J].

Wang, Dan ;

Wen, Xiao-Hui ;

Zhang, Wen-Yao ;

Sang, Shi-Hua .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2017, 62 (04) :1232-1239

[38] Mean Activity Coefficients of NaBr in Ternary System NaBr-Na2SO4-H2O Determined by the Cell Potential Method at 308.15 K [J].

Song, Yan Yu ;

Sang, Shi-Hua ;

Ge, Qi ;

Liu, Xing .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2021, 66 (01) :290-296

[39] NANO2(NANO3)-NAOH-H2O SYSTEMS [J].

PLEKHOTK.VF ;

BOBROVSK.LP .

ZHURNAL NEORGANICHESKOI KHIMII, 1970, 15 (06) :1643-&

[40] MEAN ACTIVITY-COEFFICIENTS AT 25-DEGREES-C FOR NABR-CA(NO3)2-H2O MIXTURES, A TERNARY-SYSTEM WITHOUT A COMMON ION [J].

HAGHTALAB, A ;

VERA, JH .

JOURNAL OF SOLUTION CHEMISTRY, 1991, 20 (05) :479-493

← 1 2 3 4 5 →