SYNTHESIS AND SOME REACTIONS OF MIXED (-)-MENTHYLTIN HYDRIDES

被引：31
作者：
PODESTA, JC
CHOPA, AB
RADIVOY, GE
VITALE, CA
机构：
[1] Instituto de Investigaciones en Química Orgánica, Universulad National del Sur, 8000 Bahía Blanca
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 494卷 / 1-2期
关键词：
TIN; HYDRIDES; ASYMMETRIC SYNTHESIS;
D O I：
10.1016/0022-328X(95)05323-H
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and physical properties of dineophyl(-)menthyltin (4) and methylneophyl (-)menthyltin (9) hydrides as well as that of their organotin precursors are described. Whereas the reduction of acetophenone with 4 afforded (-)-(S)-1-phenylethanol in 40% ee, the reduction of the same ketone with dimethyl(-)menthyltin hydride yielded the alcohol with only a 7% ee. Full H-1,C-13, and Sn-119 NMR data are given.
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页码：11 / 16
页数：6
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