MIXED MICELLES INVOLVING A CATIONIC FLUOROCARBON SURFACTANT

被引:20
|
作者
ESUMI, K [1 ]
机构
[1] SCI UNIV TOKYO,INST COLLOID & INTERFACE SCI,SHINJUKU KU,TOKYO 162,JAPAN
关键词
CATIONIC FLUOROCARBON SURFACTANT; MIXED CRITICAL MICELLE CONCENTRATION; REGULAR SOLUTION THEORY; VESICLE;
D O I
10.1016/0927-7757(93)02679-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Micellization of a cationic fluorocarbon surfactant with surfactants having various head groups in aqueous solution is discussed. The cationic fluorocarbon surfactant micelles can be characterized by growth from sphere to rod-like form, which is explained by counterion binding and packing ratio. Non-ideality of the mixed surfactant systems using interaction parameters obtained from a regular solution theory is greater for the cationic-cationic than for the cationic-non-ionic systems. The cationic-anionic systems show a larger negative interaction parameter and in particular, in the cationic fluorocarbon-anionic hydrocarbon mixed-system, vesicles are formed.
引用
收藏
页码:49 / 57
页数:9
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