MIXED MICELLES INVOLVING A CATIONIC FLUOROCARBON SURFACTANT

被引：20
|
作者：
ESUMI, K [1 ]
机构：
[1] SCI UNIV TOKYO,INST COLLOID & INTERFACE SCI,SHINJUKU KU,TOKYO 162,JAPAN
来源：
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1994年 / 84卷 / 01期
关键词：
CATIONIC FLUOROCARBON SURFACTANT; MIXED CRITICAL MICELLE CONCENTRATION; REGULAR SOLUTION THEORY; VESICLE;
D O I：
10.1016/0927-7757(93)02679-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Micellization of a cationic fluorocarbon surfactant with surfactants having various head groups in aqueous solution is discussed. The cationic fluorocarbon surfactant micelles can be characterized by growth from sphere to rod-like form, which is explained by counterion binding and packing ratio. Non-ideality of the mixed surfactant systems using interaction parameters obtained from a regular solution theory is greater for the cationic-cationic than for the cationic-non-ionic systems. The cationic-anionic systems show a larger negative interaction parameter and in particular, in the cationic fluorocarbon-anionic hydrocarbon mixed-system, vesicles are formed.
引用
收藏
页码：49 / 57
页数：9
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