2-STAGE KINETICS OF SINGLE-CHAIN COLLAPSE - POLYSTYRENE IN CYCLOHEXANE

被引：218

作者：

CHU, B ^{[1
]}

YING, QC ^{[1
]}

GROSBERG, AY ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST CHEM PHYS,MOSCOW 117977,RUSSIA

来源：

MACROMOLECULES | 1995年 / 28卷 / 01期

关键词：

D O I：

10.1021/ma00105a024

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two-stage kinetics of single-chain collapse was clearly observed by using a thinnest capillary-tube cell with a wall thickness of 0.01 mm and a diameter of 5 mm for dynamic light scattering (DLS) measurements. Two relaxation times, tau(crum) for the crumpled globule state and tau(eq) for the compact globule state, were determined for the first time. Experimental DLS data measured in the coil-to-globule transition were compared with theoretical predictions.

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页码：180 / 189

页数：10

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