Crystal structure of 3-methyl-2,6-bis(4-methyl-1,3-thiazol-5-yl)piperidin-4-one

被引：0
|
作者：
Manimaran, A. [1 ]
Sethusankar, K. [2 ]
Ganesan, S. [1 ]
Ananthan, S. [3 ]
机构：
[1] Orchid Chem & Pharmaceut Ltd, Res & Dev Ctr, Chennai 600119, Tamil Nadu, India
[2] RKM Vivekananda Coll Autonomous, Dept Phys, Madras 600004, Tamil Nadu, India
[3] Presidency Coll Autonomous, Dept Chem, Madras 600025, Tamil Nadu, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
crystal structure; thiazole; piperidine; zigzag chains;
D O I：
10.1107/S1600536814018856
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C14H17N3OS2, the central piperidinone ring adopts a chair conformation and the thiazole rings are inclined to its mean plane by 80.16 (12) and 67.15 (12)degrees. TheO atom and methyl group C atom deviate significantly from the mean plane of the central piperidinone ring, by 0.8138 (2) and 0.3175 (2) angstrom, respectively. The dihedral angle between the thiazole rings is 51.88 (13)degrees. In the crystal, molecules are linked via C-H center dot center dot center dot O hydrogen bonds, forming zigzag C(10) chains running parallel to [001].
引用
收藏
页码：O1055 / +
页数：7
相关论文
共 50 条
  • [41] 1-Bromo-2,6-bis(4-methylpiperazin-1-yl-methyl)benzene
    Copolovici, Lucian
    Bojan, Vilma
    Silvestru, Cristian
    Varga, Richard A.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4323 - U3423
  • [42] Crystal structure of 2,6-bis[(1H-pyrazol-1-yl)methyl]pyridine
    Son, Kyung-sun
    Woo, Jeong Oh
    Kim, Daeyoung
    Kang, Sung Kwon
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O973 - +
  • [43] Synthesis and Crystal Structure of 3,6-Bis(4-methyl-1,2,3-thiadiazol-5-yl)-1,2,4-triazolo[3,4-b] [1,3,4]thiadiazole
    Yang Zhi-Kun
    Fan Zhi-Jin
    Zuo Xiang
    Zheng Qin-Xiang
    Song Hai-Bin
    You Jin-Mao
    Natalia, P. Belskaia
    Vasiliy, A. Bakulev
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (01) : 13 - 16
  • [44] Synthesis and Crystal Structure of 3,6-Bis(4-methyl-1,2,3-thiadiazol-5-yl)-1,2,4-triazolo[3,4-b][1,3,4]thiadiazole
    杨知昆
    范志金
    左翔
    郑琴香
    宋海斌
    尤进茂
    NATALIA P.Belskaia
    VASILIY A.Bakulev
    结构化学, 2010, 29 (01) : 13 - 16
  • [45] Crystal structure of 4-methyl-5-(5-{[5-(4-methyl-2-phenyl-1,3-thiazol-5-yl)-4-phenyl-4H-1,2,4-triazol-3-yl}disulfanyl]-4-phenyl-4H-1,2,4-triazol-3-yl)-2-phenyl-1,3-thiazol acetonitrile, (C36H26N8S4)(C2H3N)
    Ramazani, A
    Morsali, A
    Jalilian, AR
    Jamali, F
    Gouranlou, F
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2002, 217 (03): : 395 - 397
  • [46] Crystal and molecular structure of 2,6-bis(4-chlorophenyl)-3-phenylpiperidin-4-one
    Ompraba, G
    Srinivasan, M
    Perumal, S
    Sekar, K
    Choudhury, AR
    Row, TNG
    Rafi, ZA
    CRYSTAL RESEARCH AND TECHNOLOGY, 2003, 38 (10) : 918 - 921
  • [47] The effect of solvent on the kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate in aqueous organic media
    Elango, KP
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2001, 66 (06) : 359 - 365
  • [48] Solvent effects on the kinetics of oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by pyridinium chlorochromate in aqueous organic medium
    Ramesh, V
    Sumathy, M
    Karunakaran, K
    Elango, KP
    OXIDATION COMMUNICATIONS, 2001, 24 (02): : 241 - 247
  • [49] Reduction of 3-hydroxymethyl-3-methyl-2,6-diphenyl-piperidin-4-one
    Kim, DG
    Tulemisova, GB
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2002, 38 (01) : 136 - 136
  • [50] One pot synthesis of 2,6-bis(2/4-hydroxyphenyl)piperidin-4-one derivatives using greener deep eutectic solvent media and their characterization
    Hemalatha, K.
    Ilangeswaran, D.
    MATERIALS TODAY-PROCEEDINGS, 2020, 33 : 4255 - 4265
12345