PHASE-SEPARATION IN QUENCHED NONCRYSTALLINE POLY(VINYLIDENE FLUORIDE) POLY(METHYL METHACRYLATE) BLENDS

被引:15
|
作者
ANDO, Y [1 ]
YOON, DY [1 ]
机构
[1] IBM CORP,ALMADEN RES CTR,SAN JOSE,CA 95120
关键词
POLY(VINYLIDENE FLUORIDE); POLY(METHYL METHACRYLATE); BLEND; CRYSTAL-AMORPHOUS INTERPHASE; PHASE SEPARATION; QUENCHING;
D O I
10.1295/polymj.24.1329
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The dielectric characterization was carried out in poly(vinylidene fluoride) (PVDF)/poly(methyl methacrylate) (PMMA) blends quenched from the melts. In the quenching of 60/40 PVDF/PMMA, the phase separation between the PVDF phase and the mixed PVDF-PMMA amorphous phase was observed in apparently completely noncrystalline blends. The dielectric behaviors for this PVDF phase separated were the same as those of the PVDF crystal-amorphous interphase. The PVDF phase/mixed amorphous phase separation was explained by forming incipient crystallites of PVDF.
引用
收藏
页码:1329 / 1336
页数:8
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