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PHASE-SEPARATION IN QUENCHED NONCRYSTALLINE POLY(VINYLIDENE FLUORIDE) POLY(METHYL METHACRYLATE) BLENDS
被引:15
|作者:
ANDO, Y
[1
]
YOON, DY
[1
]
机构:
[1] IBM CORP,ALMADEN RES CTR,SAN JOSE,CA 95120
关键词:
POLY(VINYLIDENE FLUORIDE);
POLY(METHYL METHACRYLATE);
BLEND;
CRYSTAL-AMORPHOUS INTERPHASE;
PHASE SEPARATION;
QUENCHING;
D O I:
10.1295/polymj.24.1329
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
The dielectric characterization was carried out in poly(vinylidene fluoride) (PVDF)/poly(methyl methacrylate) (PMMA) blends quenched from the melts. In the quenching of 60/40 PVDF/PMMA, the phase separation between the PVDF phase and the mixed PVDF-PMMA amorphous phase was observed in apparently completely noncrystalline blends. The dielectric behaviors for this PVDF phase separated were the same as those of the PVDF crystal-amorphous interphase. The PVDF phase/mixed amorphous phase separation was explained by forming incipient crystallites of PVDF.
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页码:1329 / 1336
页数:8
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