HYDRODYNAMIC THEORY OF MICELLAR SOLUTIONS - SUPPRESSION OF MICELLAR GROWTH BY INTERACTIONS

被引：3
|
作者：
WANG, SQ [1 ]
机构：
[1] CASE WESTERN RESERVE UNIV,DEPT PHYS,CLEVELAND,OH 44106
来源：
MACROMOLECULES | 1992年 / 25卷 / 03期
关键词：
D O I：
10.1021/ma00029a023
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A hydrodynamic theory of rigid-rod micellar solutions is presented. The previously omitted intermicelle interactions are incorporated by generalizing the Onsager theory for nematic liquid crystals to account for polydispersity and self-assembly in the presence of flow. The micellar size distribution is derived as a function of shear rate in the form of a highly nonlinear integral equation. A numerical iteration procedure has been developed to simulate the solution to this integral equation. It is found that intermicellar repulsion postpones the micellar growth (Macromolecules 1991, 24, 3004) in flow to higher shear rates.
引用
收藏
页码：1153 / 1156
页数：4
相关论文
共 50 条
  • [31] MICELLAR PROPERTIES FROM HYDRODYNAMIC DATA
    COURCHENE, WL
    JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (07): : 1870 - &
  • [32] Determination of micellar hydrodynamic radius by refraction
    Iwunze, MO
    Somerville, K
    Iwunze, R
    TENSIDE SURFACTANTS DETERGENTS, 1996, 33 (02) : 147 - 148
  • [33] Osmotic pressure and interparticle interactions in ionic micellar surfactant solutions
    Amos, DA
    Markels, JH
    Lynn, S
    Radke, CJ
    JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (15): : 2739 - 2753
  • [34] Micellar structure and inter-micelle interactions in micellar solutions: Results of small angle neutron scattering studies
    Goyal, PS
    Aswal, VK
    CURRENT SCIENCE, 2001, 80 (08): : 972 - 979
  • [35] Role of inter-micellar interaction on micellar growth
    Aswal, V.K.
    Goyal, P.S.
    Menon, S.V.G.
    Dasannacharya, B.A.
    Physica B: Condensed Matter, 1995, 213-214 : 607 - 609
  • [36] Rheology of saturated micellar networks: Wormlike micellar solutions vs. bicontinuous micellar phases
    Stancheva, Teodora N.
    Georgiev, Mihail T.
    Radulova, Gergana M.
    Danov, Krassimir D.
    Marinova, Krastanka G.
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2022, 652
  • [37] ROLE OF INTER-MICELLAR INTERACTION ON MICELLAR GROWTH
    ASWAL, VK
    GOYAL, PS
    MENON, SVG
    DASANNACHARYA, BA
    PHYSICA B, 1995, 213 : 607 - 609
  • [38] Thermal hysteresis phenomena in micellar solutions of gangliosides: Theory and experiments
    Cantu, L
    Corti, M
    delFavero, E
    Digirolamo, E
    Raudino, A
    JOURNAL DE PHYSIQUE II, 1996, 6 (07): : 1067 - 1090
  • [39] Adsorption from micellar surfactant solutions: Nonlinear theory and experiment
    Danov, KD
    Vlahovska, PM
    Horozov, T
    Dushkin, CD
    Kralchevsky, PA
    Mehreteab, A
    Broze, G
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 183 (01) : 223 - 235
  • [40] Water-Ethylene Glycol Cationic Dimeric Micellar Solutions: Aggregation, Micellar Growth, and Characteristics As Reaction Media
    Rodriguez, Amalia
    del Mar Graciani, Maria
    Cordobes, Felipe
    Luisa Moya, Maria
    JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (22): : 7767 - 7779
12345