Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-kappa N-2(3),S}- copper(II)

被引：3

作者：

Zangrando, F. ^{[1
]}

Begum, M. S. ^{[2
]}

Miyatake, R. ^{[3
]}

Sheikh, M. C. ^{[4
]}

Hossain, Md. M. ^{[2
]}

机构：

[1] Dept Chem & Pharmaceut Sci, Via Giorgieri 1, I-34127 Trieste, Italy

[2] Rajshahi Univ, Dept Chem, Rajshahi 6205, Bangladesh

[3] Toyama Univ, Ctr Environm Conservat & Res Safety, Toyama 9308555, Japan

[4] Toyama Univ, Dept Appl Chem, Fac Engn, Toyama 9308555, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; copper(II) complex; dirhiocarbazare ligand;

D O I：

10.1107/S2056989015009342

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Cu(C16H24N3S2)(2)], the Cull atom is coordinated by two azomethine N and two thiolate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S-Cu-N chelating angle is of 84.41 (5)degrees. The Cull atom is located on a crystallographic inversion centre, leading to a trans configuration of the N,S-chelating ligands.

引用

页码：706 / +

页数：8

共 15 条

[1] Biological activity of palladium(II) and platinum(II) complexes of the acetone Schiff bases of S-methyl- and S-benzyldithiocarbazate and the X-ray crystal structure of the [Pd(asme)2] (asme=anionic form of the acetone Schiff base of S-methyldithiocarbazate) complex [J].

Ali, MA ;

Mirza, AH ;

Butcher, RJ ;

Tarafder, MTH ;

Keat, TB ;

Ali, AM .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2002, 92 (3-4) :141-148

[2] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[3] Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-kappa N-2(3),S]palladium(II) [J].

Begum, M. Sabina ;

Howlader, M. Belayet Hossain ;

Sheikh, M. Chanmiya ;

Miyatake, Ryuta ;

Zangrando, Ennio .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 :M63-+

[4] Synthesis and characterization of cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II) complexes of benzyl N-[1-(thiophen-2-yl)ethylidene] hydrazine carbodithioate and benzyl N-[1-(thiophen-3-yl)ethylidene] hydrazine carbodithioate and the X-ray crystal structure of bis{benzyl N-[1-(thiophen-2-yl)ethylidene] hydrazine carbodithioate}nickel(II) [J].

Chan, Mun-Hoe Eddy ;

Crouse, Karen A. ;

Tahir, M. Ibrahim M. ;

Rosli, Rozita ;

Umar-Tsafe, Nasir ;

Cowley, Andrew R. .

POLYHEDRON, 2008, 27 (04) :1141-1149

[5] Synthesis, characterization and bio-activity of metal complexes of bidentate N-S isomeric Schiff bases derived from S-methyldithiocarbazate (SMDTC) and the X-ray structure of the bis[S-methyl-β-N-(2-furyl-methylketone) dithiocarbazato]cadmium(II) complex [J].

Chew, KB ;

Tarafder, MTH ;

Crouse, KA ;

Ali, AM ;

Yamin, BM ;

Fun, HK .

POLYHEDRON, 2004, 23 (08) :1385-1392

[6] Synthesis, characterization and bio-activity of, S-2-picolyldithiocarbazate (S2PDTC), some of its Schiff bases and their Ni(II) complexes and X-ray structure of S-2-picolyl-β-N-(2-acetylpyrrole)dithiocarbazate [J].

Crouse, KA ;

Chew, KB ;

Tarafder, MTH ;

Kasbollah, A ;

Ali, AM ;

Yamin, BM ;

Fun, HK .

POLYHEDRON, 2004, 23 (01) :161-168

[7] Synthesis, characterization and biological studies of S-benzyl-β-N-(benzoyl) dithiocarbazate and its metal complexes [J].

How, Fiona N. -F. ;

Crouse, Karen A. ;

Tahir, M. Ibrahim M. ;

Tarafder, M. T. H. ;

Cowley, Andrew R. .

POLYHEDRON, 2008, 27 (15) :3325-3329

[8] Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-kappa N-2(3), S]nickel(II) [J].

Howlader, M. B. H. ;

Begum, M. S. ;

Sheikh, M. C. ;

Miyatake, R. ;

Zangrando, E. .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 :M26-U114

[9] The Crystal Structure and Cytotoxicity of Centrosymmetric Copper(II) Complex Derived from S-methyldithiocarbazate with Isatin [J].

Manan, Mohd Abdul Fatah Abdul ;

Tahir, M. Ibrahim M. ;

Crouse, Karen A. ;

Rosli, Rozita ;

How, Fiona N. -F. ;

Watkin, David J. .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (12) :1866-1871

[10]

Rigaku, 2001, RAPID AUTO

← 1 2 →