MODEL MONOOXYGENASE REACTIVITY BY BINUCLEAR 2-COORDINATE COPPER(I) COMPLEXES EXTENDS TO NEW LIGAND SYSTEMS CONTAINING NITROGEN AND SULFUR DONORS

被引：57

作者：

CASELLA, L

GULLOTTI, M

BARTOSEK, M

PALLANZA, G

LAURENTI, E

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 18期

关键词：

D O I：

10.1039/c39910001235

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxygen insertion reaction exhibited by binuclear two-coordinate copper(I) complexes derived from bis-imine ligands extends to systems containing additional benzimidazole, tertiary amine and thioether donor groups; an inverse correlation has been found between the rate of the reaction and the basicity of the donor group.

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页码：1235 / 1237

页数：3

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