THE DELPLOT TECHNIQUE - A NEW METHOD FOR REACTION PATHWAY ANALYSIS

被引：196
作者：
BHORE, NA
KLEIN, MT
BISCHOFF, KB
机构：
[1] Mobil Research and Development Corporation, Paulsboro
[2] Center for Catalytic Science and Technology, Department of Chemical Engineering, University of Delaware, Newark
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1990年 / 29卷 / 02期
关键词：
D O I：
10.1021/ie00098a025
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A method for discernment of the rank (i.e., primary, secondary, etc.) of a reaction product is developed. The first-rank “delplot” method allows separation of primary from nonprimary products for any reaction order. Higher rank products (secondary, tertiary, etc.) can be separated by using (a) higher rank delplots, which are applicable for first-order and many other kinetic expressions, or (b) successive application of the first-rank delplot method. © 1990, American Chemical Society. All rights reserved.
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页码：313 / 316
页数：4
相关论文
共 14 条
[1]  
AKELLA IM, 1981, CHEM ENG J, V22, P25
[2]  
BHORE NA, 1989, THESIS U DELAWARE NE
[3]  
Carberry J.J., 1976, CHEM CATALYTIC REACT
[4]  
DRAPER NR, 1966, APPLIED REGRESSION A
[5]  
Froment G.F., 1979, CHEM REACTOR ANAL DE
[6]  
HOFMANN H, 1985, APPL CATAL, V15, P79
[7]  
HOSTEN LH, 1986, RECENT ADV ENG ANAL
[8]  
Hougen O. A., 1947, CHEM PROCESS PRINC 3
[9]   MODEL PATHWAYS IN LIGNIN THERMOLYSIS .1. PHENETHYL PHENYL ETHER [J].
KLEIN, MT ;
VIRK, PS .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1983, 22 (01) :35-45
[10]  
Lee H.H., 1985, HETEROGENEOUS REACTO
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