BICYCLO[3.2.1]OCTENONES AS BUILDING-BLOCKS IN NATURAL-PRODUCTS SYNTHESIS .3. TOTAL SYNTHESIS OF (+/-)-10-DEOXYGENIPOSIDE AGLUCONE

被引：5

作者：

HSU, LF

CHANG, NC

机构：

[1] Department of Chemistry, National Sun Yat-Sen University, Kaohsiung

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1994年 / 41卷 / 05期

关键词：

IRIDOIDS; BICYCLO[3.2.1]OCTENONES; BICYCLE[3.3.0]OCTENONES; (+/-)-10-DEOXYGENIPOSIDE AGLUCONE; PHOTOCHEMICAL REARRANGEMENT OF BETA; GAMMA-UNSATURATED KETONE; MONOTERPENES; CYCLOPENTANPYRAN;

D O I：

10.1002/jccs.199400083

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound was synthesized from bicyclo[3.2.1]octenone 1 in six steps and in overall yield 59%. Photochemical rearrangement of beta,gamma-unsaturated enone 1 is the key step.

引用

页码：609 / 611

页数：3

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