NEW MONOSPIROCYCLOTRIPHOSPHAZENES AND TRISPIROCYCLOTRIPHOSPHAZENES FROM THE REACTIONS OF (NPCL2)3 WITH AROMATIC ORTHO DINUCLEOPHILES

被引：54
作者：
ALLCOCK, HR
DIEFENBACH, U
PUCHER, SR
机构：
[1] Department of Chemistry, Pennsylvania State University, University Park
来源：
INORGANIC CHEMISTRY | 1994年 / 33卷 / 14期
关键词：
D O I：
10.1021/ic00092a013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, P-31 NMR, and H-1 NMR spectroscopy, mass spectrometry, and elemental analysis.
引用
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页码：3091 / 3095
页数：5
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