KINETIC-STUDIES ON THE NORMAL-ALKYL ACRYLATE POLYMERIZATION

被引：15

作者：

SUBRAHMANYAM, B ^{[1
]}

BARUAH, SD ^{[1
]}

RAHMAN, M ^{[1
]}

BARUAH, JN ^{[1
]}

DASS, NN ^{[1
]}

机构：

[1] DIBRUGARH UNIV,DEPT CHEM,DIBRUGARH 786004,ASSAM,INDIA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1992年 / 30卷 / 12期

关键词：

POUR POINT DEPRESSANTS; ALKYL ACRYLATES; NORMAL-BUTYL ACRYLATE; NORMAL-OCTADECYL ACRYLATE; POLYMERIZATION; KINETIC ORDERS; ACTIVATION ENERGY; AUTOACCELERATION;

D O I：

10.1002/pola.1992.080301207

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Kinetic studies on the polymerization of n-butyl acrylate and n-octadecyl acrylate in toluene at 70-degrees-C with benzoyl peroxide as initiator are reported. High monomer orders of 1.55 and 1.75 were obtained for n-butyl and n-octadecyl acrylates, respectively. Though the initiator order in butyl acrylate polymerization was 0.5, the octadecyl acrylate polymerization showed less than square root initiator order. The activation energy for the polymerization of both the acrylates was determined. Autoacceleration was found even at low conversions. The autoacceleration was influenced by both monomer and initiator concentration. Molecular weight data was presented in support of the gel effect.

引用

页码：2531 / 2549

页数：19