SYNTHESIS OF POLY(HEMISPHERAND) VIA CYCLOPOLYMERIZATION OF DIEPOXIDE

被引：4

作者：

KAKUCHI, T ^{[1
]}

HABA, O ^{[1
]}

HARADA, Y ^{[1
]}

HASHIMOTO, H ^{[1
]}

YOKOTA, K ^{[1
]}

机构：

[1] TOMAKOMAI NATL COLL TECHNOL,DEPT IND CHEM,TOMAKOMAI 05912,JAPAN

来源：

POLYMER BULLETIN | 1992年 / 27卷 / 06期

关键词：

D O I：

10.1007/BF00297428

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Cyclopolymerization of 2,6-bis[3-(4,5-epoxy-2-oxapentyl)-2-methoxy-5-methylphenyl]-4-methylanisole was carried out with cationic, anionic, and coordination catalysts. The polymers obtained with BF3.OEt2 or SnCl4 in dichloromethane and with t-BuOK in DMSO were soluble in benzene, chloroform, and THF. The mole fractions of the cyclic units in these polymers were from 0.65 to 0.75. The resulting poly(hemispherand) bound alkali metal cations and the selectivity was in the order of Rb+ > K+ > Cs+ > Na+ > Li+.

引用

页码：599 / 605

页数：7

共 50 条

[31] Synthesis and Properties of Photodegradable Poly(furan-amine)s by a Catalyst-free Multicomponent Cyclopolymerization
Wei-Qiang Fu
Gui-Nan Zhu
Jian-Bing Shi
Bin Tong
Zheng-Xu Cai
Yu-Ping Dong
Chinese Journal of Polymer Science , 2019, (10) : 981 - 1002
[32] Preparation and properties of elastomers based on a cycloaliphatic diepoxide and poly(tetrahydrofuran)
Hartwig, A
Sebald, M
EUROPEAN POLYMER JOURNAL, 2003, 39 (10) : 1975 - 1981
[33] Cyclopolymerization protocol for the synthesis of a poly(zwitterion-alt-sulfur dioxide) to investigate the polyzwitterion-to-poly(anion-zwitterion) transition
Ali, Shaikh A.
Haladu, Shamsuddeen A.
JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 129 (03) : 1394 - 1404
[34] Stereocontrol of vinyl polymers via cyclopolymerization.
Zheng, SY
Sogah, DY
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 3 - POLY
[35] Synthesis, Structure and Attempted Polymerization of a Diepoxide Macrocycle
Yarincik, Paul
Glans, Jeffrey H.
LETTERS IN ORGANIC CHEMISTRY, 2012, 9 (08) : 545 - 548
[36] Cyclopolymerization protocol for the synthesis of a poly(zwitterion-alt- sulfur dioxide) to investigate the polyzwitterion-to-poly(anion-zwitterion) transition
Ali, S.A. (shaikh@kfupm.edu.sa), 1600, John Wiley and Sons Inc (129):
[37] SYNTHESIS AND PHOTOPOLYMERIZATION OF A LIQUID-CRYSTALLINE DIEPOXIDE
BROER, DJ
LUB, J
MOL, GN
MACROMOLECULES, 1993, 26 (06) : 1244 - 1247
[38] POLYMERIC CHIRAL CROWN ETHERS .8. SYNTHESIS OF OPTICALLY-ACTIVE POLY(DIBENZO-19-CROWN-6)S VIA CYCLOPOLYMERIZATION OF DIEPOXIDES
HASHIMOTO, H
KAKUCHI, T
HABA, O
YOKOTA, K
MACROMOLECULES, 1992, 25 (06) : 1828 - 1831
[39] SYNTHESIS AND CYCLOPOLYMERIZATION OF 1,8-DIVINYLNAPHTHALENE
STILLE, JK
FOSTER, RT
JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (10): : 2703 - &
[40] DYNAMIC-MECHANICAL PROPERTIES OF POLY(OXYPROPYLENE)DIAMINE-DIEPOXIDE AND POLY(OXYPROPYLENE)TRIAMINE-DIEPOXIDE NETWORKS AND THEIR RELATIONSHIP TO THE STRUCTURE OF ELASTICALLY ACTIVE NETWORK CHAINS
ILAVSKY, M
HROUZ, J
SOMVARSKY, J
DUSEK, K
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1989, 30 : 13 - 30

← 1 2 3 4 5 →