C-13 NMR CHEMICAL-SHIFT CORRELATIONS IN 1,3-DIOL ACETONIDES - IMPLICATIONS FOR THE STEREOCHEMICAL ASSIGNMENT OF PROPIONATE-DERIVED POLYOLS

被引：380
作者：
EVANS, DA
RIEGER, DL
GAGE, JR
机构：
[1] Department of Chemistry, Harvard University, Cambridge
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 49期
关键词：
D O I：
10.1016/S0040-4039(00)97250-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Rychnovsky's recent correlation of the stereochemistry-dependent 13C NMR chemical shifts of 4,6-disubstituted 1,3-diol acetonides with diol stereochemistry may be extended to more highly substituted dioxolanes bearing substituents in the 5-position. The 13C resonances of the acetonide carbons follow a predictable, stereoregular pattern which depends solely on the diol stereochemical relationship. © 1990.
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页码：7099 / 7100
页数：2
相关论文
共 3 条
[1]  
DIMARE MM, 1988, THESIS HARVARD U
[2]  
DOW RL, 1985, THESIS HARVARD U
[3]   STEREOCHEMISTRY OF ALTERNATING POLYOL CHAINS - C-13 NMR ANALYSIS OF 1,3-DIOL ACETONIDES [J].
RYCHNOVSKY, SD ;
SKALITZKY, DJ .
TETRAHEDRON LETTERS, 1990, 31 (07) :945-948
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