Synthesis and Surface Activity of Some Cationic Gemini Surfactants Containing Aliphatic Spacers

被引:0
作者
Zahran, M. K. [1 ]
Negm, N. A. [2 ]
Mahmoud, W. A. [3 ]
机构
[1] Helwan Univ, Fac Sci, Cairo, Egypt
[2] Egyptian Petr Res Inst, Petrochem Dept, Cairo, Egypt
[3] Egyptian Nat Gas Holding Co, Cairo, Egypt
来源
EGYPTIAN JOURNAL OF CHEMISTRY | 2013年 / 56卷 / 01期
关键词
Gemini surfactants; Spacer group; Surface activity and Thermodynamics;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
FOUR CATIONIC Gemini surfactants were synthesized and characterized using different tools. Their surface activities were measured using surface and interfacial tension measurements. The effect of their spacer chain length on the surface activity, emulsification power and interfacial tension was studied. The thermodynamic parameters showed the tendency towards micellization and adsorption. The results showed that longer spacers increased the micellization tendencies of the surfactants, while shorter spacers increased the adsorption propensity at the air-water interface.
引用
收藏
页码:35 / 47
页数:13
相关论文
共 37 条
[1]   Synthesis and Surface Active Properties of Gemini Cationic Surfactants and Interaction with Anionic Azo Dye (AR52) [J].
Abdel-Salam, Fatma H. ;
El-Said, Asrar G. .
JOURNAL OF SURFACTANTS AND DETERGENTS, 2011, 14 (03) :371-379
[2]   Synthesis and characterization of new cationic surfactants derived from lactic acid [J].
Anoune, N ;
Nouiri, M ;
Arnaud, C ;
Petit, S ;
Lanteri, P .
JOURNAL OF SURFACTANTS AND DETERGENTS, 2000, 3 (03) :381-386
[3]   Mixed micellization of an anionic gemini surfactant (GA) with conventional polyethoxylated nonionic surfactants in brine solution at pH 5 and 298 K [J].
Chakraborty, Tanushree ;
Ghosh, Soumen .
COLLOID AND POLYMER SCIENCE, 2007, 285 (15) :1665-1673
[4]   Interaction Between Nonionic and Gemini (Cationic) Surfactants: Effect of Spacer Chain Length [J].
Chavda, Suresh ;
Bahadur, Pratap ;
Aswal, Vinod K. .
JOURNAL OF SURFACTANTS AND DETERGENTS, 2011, 14 (03) :353-362
[5]  
Cross J., 1994, CATIONIC SURFACTANTS, DOI DOI 10.1201/9780367813130
[6]   Head-group size or hydrophilicity of surfactants: The major regulator of lipase activity in cationic water-in-oil microemulsions [J].
Das, D ;
Roy, S ;
Mitra, RN ;
Dasgupta, A ;
Das, PK .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (17) :4881-4889
[7]   Aqueous properties of multichain quaternary cationic surfactants [J].
Esumi, K ;
Taguma, K ;
Koide, Y .
LANGMUIR, 1996, 12 (16) :4039-4041
[8]   Effects of Head Group of Cationic Surfactants on the Hydrolysis of p-Nitrophenyl Acetate Catalyzed by α-Chymotrypsin [J].
Ghosh, Kallol K. ;
Verma, Santosh Kumar .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2009, 41 (06) :377-381
[9]  
Ghosh KK, 2008, INDIAN J BIOCHEM BIO, V45, P350
[10]   Nucleophilic dephosphorylation of p-nitrophenyl diphenyl phosphate in cationic micellar media [J].
Ghosh, KK ;
Sinha, D ;
Satnami, ML ;
Dubey, DK ;
Rodriguez-Dafonte, P ;
Mundhara, GL .
LANGMUIR, 2005, 21 (19) :8664-8669