IONIC IRIDIUM-GOLD AND RHODIUM-GOLD PERFLUOROBENZENETHIOLATO BINUCLEAR COMPLEXES - SYNTHESES AND SOLUTION BEHAVIOR

被引：7

作者：

GARCIA, JJ ^{[1
]}

HERNANDEZ, ML ^{[1
]}

TORRENS, H ^{[1
]}

GUTIERREZ, A ^{[1
]}

DELRIO, F ^{[1
]}

机构：

[1] UNIV NACL AUTONOMA MEXICO,INST QUIM,MEXICO CITY 04510,DF,MEXICO

来源：

INORGANICA CHIMICA ACTA | 1995年 / 230卷 / 1-2期

关键词：

IRIDIUM COMPLEXES; RHODIUM COMPLEXES; GOLD COMPLEXES; THIOLATO COMPLEXES; BINUCLEAR COMPLEXES; PENTAMETHYLCYCLOPENTADIENYL;

D O I：

10.1016/0020-1693(94)04195-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By reacting [(C(5)Me(5))M(SR(F))(2)] (for M=Ir, R(F)=C6F5 (1a) or C6F4H-p (1b); for M=Rh, R(F)=C6F5 (2a) or C6F4H-p (2b)) in toluene with Na[AuCl4], ionic binuclear compounds with the general formula [(C(5)Me(5))M(mu-SR(F))(2)AuCl2]Cl (for M=Ir, R(F)=C6F5 (3a) or C6F4H-p (3b)); for M=Rh, R(F)=C6F5 (4a) or C6F4H-p (4b) can be obtained, together with small amounts of [(C(5)Me(5))(2)Rh-2(mu-SR(F))(mu-Cl)(2)]Cl (R(F)=C6F5 (5a) or C6F4H-p (5b)) as by-products when 2a and 2b were used.

引用

页码：173 / 176

页数：4

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