A STERICALLY HINDERED AND HIGHLY LIPOPHILIC METALLOPORPHYRIN - CRYSTAL AND MOLECULAR-STRUCTURE OF MESO-TETRAKIS(3,5-DI-T-BUTYLPHENYL)PORPHYRIN-IRIDIUM(III) CARBONYL CHLORIDE

被引：8

作者：

CHAN, KS ^{[1
]}

CHEN, XM ^{[1
]}

MAK, TCW ^{[1
]}

机构：

[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG

来源：

POLYHEDRON | 1992年 / 11卷 / 20期

关键词：

D O I：

10.1016/S0277-5387(00)80242-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex was synthesized and characterized by single-crystal X-ray analysis. The iridium(III) atom is coordinated by four nitrogen atoms in a square-planar fashion with Ir-N = 2.04(1) angstrom, and the coordination sphere is completed by chloro and carbonyl ligands at the axial positions with Ir-Cl = 2.293(6), Ir-C = 1.95(2) angstrom and Cl-Ir-C = 172.7(6)-degrees. The porphyrin ring is nearly planar with the dihedral angle between adjacent pyrrole rings at only 1.2-degrees. The dihedral angles between the porphyrin ring and the phenyl rings lie in the range 68.3-81.8-degrees.

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页码：2703 / 2706

页数：4

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