COMPLEX-FORMATION OF GOLD WITH N,N-DIALKYL-N'-BENZOYLTHIOUREAS - THE CRYSTAL-STRUCTURE OF N,N-DIETHYL-N'-BENZOYLTHIOUREATOGOLD(I) CHLORIDE

被引：50

作者：

BENSCH, W

SCHUSTER, M

机构：

[1] Institut für Anorganische Chemie der Universität, Frankfurt/M.

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 611卷 / 05期

关键词：

N; N-DIETHYL-N'-BENZOYLTHIOUREATOGOLD(I); CHLORIDE; PREPARATION; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19926110517

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N,N-Diethyl-N'-benzoylthioureatogold(I) chloride AuClS12H16N2O crystallizes in the monoclinic space group P2(1)/c. The cell parameters are a = 18.407(4), b = 5.456(1) and c = 16.322(3) angstrom, beta = 113.68(1)-degrees. The structure was solved with direct techniques and refined to final R-value of 5.92%. Gold(I) forms a monodentately sulfur-coordinated complex with the ligand N,N-Diethyl-N'-benzoylthiourea. The coordination sphere around Au(I) shows a nearly linear arrangement of sulfur and chloride.

引用

页码：99 / 102

页数：4

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