SOLVENT DEPENDENCE OF CHARGE-TRANSFER TRANSITIONS IN BINARY AQUEOUS MIXTURES

被引：7
作者：
MOYA, ML
RODRIGUEZ, A
机构：
[1] Departamento de Química Física, Universidad de Sevilla, Profesor García González s/n 41012, Sevilla
来源：
TRANSITION METAL CHEMISTRY | 1991年 / 16卷 / 02期
关键词：
D O I：
10.1007/BF01032841
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Charge-transfer transitions of Ru(bipy)3(2+), Fe(bipy)3(2+), Fe(CN)6(3-), and free bipy (bipy = 2,2'-bipyridine) are solvent dependent. Evidence is presented that dielectric continuum theory provides a reasonable basis for interpreting medium effects on the electronic transition energies in binary solvent mixtures as well as in pure solvents.
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页码：230 / 235
页数：6
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