INFLUENCE OF MOLECULAR ORDERING ON THE PRESSURE BEHAVIOR OF THE NEMATIC-ISOTROPIC TRANSITION

被引:10
作者
KLEINHANS, HD
SHASHIDHAR, R
SCHNEIDER, GM
机构
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1982年 / 82卷 / 01期
关键词
D O I
10.1080/01406568208070507
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The effect of pressure on the nematic-isotropic transition in mixtures of 60CB and 80CB has been studied by DTA. The plot of dT/dp at 1 bar versus molefraction (x) of 60CB shows an anomalous decrease in the range 0. 1 less than x less than 0. 28. Experiments conducted under different thermal conditions of the sample seem to indicate that this anomalous behavior is essentially due to the influence of molecular ordering which develops continuously and not due to any kinetic effects.
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页码:19 / 24
页数:6
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