AROMATIC GALLIUM HETEROCYCLES - SYNTHESIS OF THE FIRST GALLATABENZENE

被引：32

作者：

ASHE, AJ

ALAHMAD, S

KAMPF, JW

机构：

[1] Department of Chemistry, University of Michigan, Ann Arbor, Michigan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 12期

关键词：

ARENE COMPLEXES; GALLIUM COMPOUNDS; HETEROCYCLES; MANGANESE COMPOUNDS;

D O I：

10.1002/anie.199513571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deprotonation of the conjugate acid 2 led to the first gallatabenzene 1. The acidity of 2 and the low‐field shift of the NMR signals of the ring protons of 1 relative to the corresponding properties of cyclohexadienide suggest that 1 has aromatic character. The heterocycle of 1 can function as a ligand and was coordinated to a Mn(CO)3 fragment. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

收藏

页码：1357 / 1359

页数：3

相关论文

共 26 条

[1] BIS(1-SUBSTITUTED-BORABENZENE)IRON COMPLEXES [J].

ASHE, AJ ;

MEYERS, E ;

SHU, P ;

VONLEHMANN, T ;

BASTIDE, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (23) :6865-6866

[2] 1-PHENYLBORABENZENE ANION [J].

ASHE, AJ ;

SHU, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (07) :1804-&

[3] ACIDITIES OF CARBON AND NITROGEN ACIDS - THE AROMATICITY OF THE CYCLOPENTADIENYL ANION [J].

BORDWELL, FG ;

DRUCKER, GE ;

FRIED, HE .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (03) :632-635

[4] CRYSTAL AND MOLECULAR STRUCTURE OF PI-CYCLOHEXADIENYLMANGANESE TRICARBONYL [J].

CHURCHILL, MR ;

SCHOLER, FR .

INORGANIC CHEMISTRY, 1969, 8 (09) :1950-+

[5]

Cowley A. H., 1994, ANGEW CHEM, V106, P1429

[6] REACTIONS OF A BULKY ARYLGALLIUM DICHLORIDE WITH ORGANOMETALLIC MONOANIONS - FORMATION OF A DIGALLOXANE WITH ORGANOMETALLIC SUBSTITUENTS [J].

COWLEY, AH ;

DECKEN, A ;

OLAZABAL, CA ;

NORMAN, NC .

INORGANIC CHEMISTRY, 1994, 33 (16) :3435-3437

[7] REACTIVITY OF A PHOSPHANYLCARBENE (LAMBDA(5)-PHOSPHAACETYLENE) WITH LEWIS-ACIDS - X-RAY CRYSTAL-STRUCTURES OF THE FIRST CARBENE-GALLANE COMPLEX AND C-GALLYL-SUBSTITUTED PHOSPHORUS YLIDE [J].

COWLEY, AH ;

GABBAI, FP ;

CARRANO, CJ ;

MOKRY, LM ;

BOND, MR ;

BERTRAND, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (05) :578-580

[8]

COWLEY AH, 1994, ANGEW CHEM INT EDIT, V33, P1370, DOI 10.1002/anie.199413701

[9]

COWLEY AH, 1994, ANGEW CHEM, V106, P584

[10] NOVEL AROMATIC BORON HETEROCYCLE AS LIGAND IN A TRANSITION METAL PI-COMPLEX [J].

HERBERIC.GE ;

GREISS, G ;

HEIL, HF .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1970, 9 (10) :805-&