EXCITED-STATE ELECTRIC-DIPOLE POLARIZABILITIES AND MOMENTS BY SOLVENT SPECTRAL FREQUENCY-SHIFTS - ANILINE, PHENOL AND NAPHTHALENE

被引:10
作者
IWEIBO, I
CHONGWAIN, PT
OBIEGBEDI, NO
LESI, AF
机构
[1] Department of Chemistry, University of Ibadan, Ibadan
来源
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1991年 / 47卷 / 06期
关键词
D O I
10.1016/0584-8539(91)80140-E
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The solvent spectral frequency shift theory of ABE in its rigorous or unqualified form has been used to determine the electric dipole polarizabilities and moments of some of the excited electronic states of aniline, phenol and naphthalene. The results of the present analysis show the internal consistency of ABE's solvatochromic method and are largely in reasonable agreement with those determined by means of electro-optical measurements and/or molecular orbital calculations.
引用
收藏
页码:705 / 712
页数:8
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