EXCITED-STATE ELECTRIC-DIPOLE POLARIZABILITIES AND MOMENTS BY SOLVENT SPECTRAL FREQUENCY-SHIFTS - ANILINE, PHENOL AND NAPHTHALENE

被引：10
作者：
IWEIBO, I
CHONGWAIN, PT
OBIEGBEDI, NO
LESI, AF
机构：
[1] Department of Chemistry, University of Ibadan, Ibadan
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1991年 / 47卷 / 06期
关键词：
D O I：
10.1016/0584-8539(91)80140-E
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The solvent spectral frequency shift theory of ABE in its rigorous or unqualified form has been used to determine the electric dipole polarizabilities and moments of some of the excited electronic states of aniline, phenol and naphthalene. The results of the present analysis show the internal consistency of ABE's solvatochromic method and are largely in reasonable agreement with those determined by means of electro-optical measurements and/or molecular orbital calculations.
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页码：705 / 712
页数：8
相关论文
共 38 条
[1]   COMPARISON OF THE EXCITED-STATE DIPOLE-MOMENTS AND POLARIZABILITIES ESTIMATED FROM SOLVENT SPECTRAL SHIFTS WITH THOSE FROM ELECTROOPTICAL MEASUREMENTS [J].
ABE, T ;
IWEIBO, I .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (12) :3415-3422
[2]   THEORY OF SOLVENT EFFECTS ON MOLECULAR ELECTRONIC SPECTRA . FREQUENCY SHIFTS [J].
ABE, T .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1965, 38 (08) :1314-+
[3]   DIPOLE MOMENTS AND POLARIZABILITIES IN EXCITED STATES OF NAPHTHALENE FROM SPECTRAL SOLVENT SHIFTS [J].
ABE, T ;
AMAKO, Y ;
NISHIOKA, T ;
AZUMI, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1966, 39 (04) :845-+
[4]   SELF-CONSISTENT PERTURBATION THEORY FOR CONJUGATED MOLECULES .2. ANISOTROPIC ELECTRIC POLARIZABILITIES OF CONJUGATED MOLECULES [J].
AMOS, AT ;
HALL, GG .
THEORETICA CHIMICA ACTA, 1966, 6 (02) :159-&
[5]  
AMOS AT, 1972, THEOR CHIM ACTA, V3, P327
[6]   DETERMINATION OF EXCITED-STATE ELECTRIC-DIPOLE MOMENT OF A MOLECULE FROM SOLVATOCHROMIC SHIFT MEASUREMENTS - A NEW APPROACH [J].
AYACHIT, NH ;
DESHPANDE, DK ;
SHASHIDHAR, MA ;
RAO, KS .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1986, 42 (12) :1405-1406
[7]   ELECTRONIC SPECTRA OF SUBSTITUTED AROMATIC HYDROCARBONS .1. PHENOL AND ANILINE [J].
BABA, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1961, 34 (01) :76-82
[8]   VAN DER WAALS VOLUMES + RADII [J].
BONDI, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+
[9]  
HARRISON RD, 1972, BOOK DATA, P90
[10]   ELECTRONIC ABSORPTION-SPECTRA AND STRUCTURES OF ANILINE AND ITS 4-CHLORO, PENTAFLUORO AND PENTACHLORO DERIVATIVES [J].
IWEIBO, I ;
ODERINDE, RA ;
FANIRAN, JA .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1982, 38 (01) :1-7
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