DIHAPTO-ACYL DERIVATIVES OF RUTHENIUM(II) - PREPARATION AND STRUCTURE OF RU[ETA-2-C(O)CH3]I(CO) (PPH3)2 AND RU[ETA-2-C(O) PARA-TOLYL]I(CO) (PPH3)2

被引：102

作者：

ROPER, WR

TAYLOR, GE

WATERS, JM

WRIGHT, LJ

机构：

[1] Department of Chemistry, University of Auckland, Auckland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)84832-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction between Ru(CO)2(PPh3)3 and MeHgI yields Ru[η2-C(O)CH3]I(CO)(PPh3)2 which in solution exists mainly as RuCH3I(CO)2(PPh3)2 and crystal structure determination of Ru[η2-C(O)CH3]I(CO)(PPh3)2 and previously described Ru[η2-C(O)p-tolyl]I(CO) (PPh3)2 confirms that in the solid state both molecules contain dihapto-acyl ligands. © 1979.

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页码：C46 / C48

页数：3

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