Importance of ionic liquid-doped solid polymer (PVPI) electrolyte

被引：3
作者：
Singh, Pramod K. [1 ]
机构：
[1] Sharda Univ, Sch Engn & Technol, Dept Phys, Mat Res Lab, Greater Noida 201306, India
来源：
INTERNATIONAL JOURNAL OF SUSTAINABLE ENERGY | 2011年 / 30卷 / 05期
关键词：
nanoporous film; SEM; TEM; AFM; ionic conductivity; dye-sensitized solar cell;
D O I：
10.1080/1478646X.2010.509502
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The aim of the present work is to synthesize a porous nanocrystalline TiO2 electrode and to use a new kind of solid polymer electrolyte, poly(N-methyl 4-vinylpyridine iodide), doped with an ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethane sulphonyl) imide, for dye-sensitized solar cell (DSSC) applications. The fabrication process of nanoporous TiO2 electrode and electrical, structural and photoelectrochemical properties of polymer electrolytes are presented in detail. A novel DSSC has also been fabricated, which shows overall efficiency of 0.56% at one sun condition.
引用
收藏
页码：270 / 276
页数：7
相关论文
共 20 条
[1]   Effect of Cation Size on Solid Polymer Electrolyte Based Dye-Sensitized Solar Cells [J].
Bhattacharya, Bhaskar ;
Lee, Jun Young ;
Geng, Jianxin ;
Jung, Hee-Tae ;
Park, Jung-Ki .
LANGMUIR, 2009, 25 (05) :3276-3281
[2]   Electrochemical and Structural Characterization of Polymer Gel Electrolytes Based on a PEO Copolymer and an Imidazolium-Based Ionic Liquid for Dye-Sensitized Solar Cells [J].
Freitas, Flavio S. ;
de Freitas, Jilian N. ;
Ito, Bruno I. ;
De Paoli, Marco-A. ;
Nogueira, Ana F. .
ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (12) :2870-2877
[3]   Recent Advances in Sensitized Mesoscopic Solar Cells [J].
Graetzel, Michael .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1788-1798
[4]   Azide-induced crosslinking of electrolytes and its application in solid-state dye-sensitized solar cells [J].
Koh, Joo Hwan ;
Koh, Jong Kwan ;
Park, Nam-Gyu ;
Kim, Jong Hak .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (03) :436-441
[5]   Poly(ethylene oxide)/poly(dimethylsiloxane) blend solid polymer electrolyte and its dye-sensitized solar cell applications [J].
Lee, Jun Young ;
Bhattacharya, Bhaskar ;
Kim, Dong-Won ;
Park, Jung-Ki .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (32) :12576-12582
[6]  
Longo C, 2003, J BRAZIL CHEM SOC, V14, P889
[7]  
Macdonald JR., 1987, IMPEDANCE SPECTROSCO
[8]   Polymers in dye sensitized solar cells: overview and perspectives [J].
Nogueira, AF ;
Longo, C ;
De Paoli, MA .
COORDINATION CHEMISTRY REVIEWS, 2004, 248 (13-14) :1455-1468
[9]  
Nogueira AF, 2001, ADV MATER, V13, P826, DOI 10.1002/1521-4095(200106)13:11<826::AID-ADMA826>3.0.CO
[10]  
2-L
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