CRYSTALLINE ALKYL-LITHIUMS FROM ALPHA-TRIMETHYLSILYL-SUBSTITUTED ORTHO-XYLENES - X-RAY CRYSTAL-STRUCTURE OF [(ORTHO-C6H4(CHSIME3)2)(LI(TMEDA))2] (TMEDA=ME2NCH2CH2NME2)

被引：67

作者：

LAPPERT, MF ^{[1
]}

RASTON, CL ^{[1
]}

SKELTON, BW ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT PHYS & INORGAN CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1982年 / 01期

关键词：

D O I：

10.1039/c39820000014

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：14 / 15

页数：2

共 11 条

[1] STRUCTURE OF CRYSTALLINE (HEXATRIENE DIANION) DILITHIUM, AN ION-PAIRED Z,Z-DIANION [J].

ARORA, SK ;

BATES, RB ;

BEAVERS, WA ;

CUTLER, RS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (21) :6271-6272

[2] PI GROUPS IN ION-PAIR BONDING - STABILIZATION OF DIANION OF NAPHTHALENE BY LITHIUM TETRAMETHYLETHYLENEDIAMINE [J].

BROOKS, JJ ;

RHINE, W ;

STUCKY, GD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (21) :7346-&

[3] TRIS(TRIMETHYLSILYL)METHYL!LITHIUM - AN ALKYLLITHIUM COMPOUND OF UNUSUAL STABILITY [J].

COOK, MA ;

EABORN, C ;

JUKES, AE ;

WALTON, DRM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 24 (03) :529-&

[4] METALATIONS .16. POLYLITHIATION AT BENZYLIC POSITIONS [J].

KLEIN, J ;

MEDLIK, A ;

MEYER, AY .

TETRAHEDRON, 1976, 32 (01) :51-56

[5] METAL-COMPLEXES DERIVED FROM A BIDENTATE LIGAND POSSESSING 2 CHIRAL CENTERS, OMICRON-C6H4[CH(SIME3)-]2 - STEREOSPECIFIC SYNTHESIS OF THE MESO-METALLOCYCLES [M[CH(SIME3)C6H4CH(SIME3)-OMOCRON](ETA-C5H5)2] AND THEIR REVERSIBLE ONE-ELECTRON REDUCTION [J].

LAPPERT, MF ;

RASTON, CL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (24) :1284-1285

[6] A ZIRCONOCENE(IV) CHLORO-ALKYL AND DIALKYL CONTAINING CHIRAL ALPHA-CARBON ATOMS, [ZR(ETA-C5H5)2(RSTAR)(X)][RSTAR=CH(SIME3)C6H4ME-OMICRON,X=CLORRSTAR] - SYNTHESIS, STEREOISOMERISM, AND D1 REDUCTION PRODUCTS [J].

LAPPERT, MF ;

RASTON, CL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (04) :173-175

[7] CARBANIONS REARRANGEMENT BY INTRAMOLECULAR 1-OMEGA-PROTON SHIFT .2. REACTIVITY OF 3-LTHIOALKYLTRIMETHYLSILANE, 4-LTHIOALKYLTRIMETHYLSILANE AND 5-LTHIOALKYLTRIMETHYLSILANE [J].

MAERCKER, A ;

ECKERS, M ;

PASSLACK, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 186 (02) :193-205

[8] METALATION OF BIS(CYCLOPENTADIENYL) METAL HYDRIDES BY ETA-BUTYLLITHIUM IN THE PRESENCE OF PENTAMETHYLDIETHYLENETRIAMINE - SYNTHESIS OF BIS(CYCLOPENTADIENYL)RHENIUM ALKYLS AND THE MIXED METAL-COMPLEXES - ETA-5-C5H5)2M(MU-CO)2RE(CO)ETA-5-C5H5)(M = MO, W) [J].

MINK, RI ;

WELTER, JJ ;

YOUNG, PR ;

STUCKY, GD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (23) :6928-6933

[9] LITHIATION OF TRIS(TRIMETHYLSILYL)METHANE AND TETRAKIS-(TRIMETHYLSILYL)METHANE [J].

STEWARD, OW ;

JOHNSON, JS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 55 (02) :209-213

[10] ALPHA-ALPHA'-DIMETALATIONS OF DIMETHYLARENES WITH ORGANOSODIUM REAGENTS - CATALYTIC EFFECT OF CERTAIN TERTIARY-AMINES [J].

TRIMITSI.GB ;

TUNCAY, A ;

BEYER, RD ;

KETTERMA.KJ .

JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (08) :1491-1496

← 1 2 →