METHANOL OXIDATION TO FORMALDEHYDE ON BISMUTH PHOSPHATE-BASED CATALYSTS

被引：14

作者：

ABADZHJIEVA, N

TZOKOV, P

UZUNOV, I

MINKOV, V

KLISSURSKI, D

RIVES, V

机构：

[1] BULGARIAN ACAD SCI,INST ORGAN CHEM,BU-1113 SOFIA,BULGARIA

[2] UNIV SALAMANCA,FAC FARM,DEPT QUIM INORGAN,E-37007 SALAMANCA,SPAIN

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1994年 / 53卷 / 02期

关键词：

D O I：

10.1007/BF02073050

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A bismuth (III) phosphate catalyst has been prepared by precipitation and characterized by X-ray diffraction, thermogravimetric analysis, and X-ray photoelectron and infrared spectroscopy. Its activity and selectivity toward selective methanol oxidation to formaldehyde has been studied by a flow method. A high selectivity has been found, similar to that reported for typical catalysts used for this reaction. The possible importance of the strength and covalency of the P-O bonds is discussed.

引用

页码：413 / 418

页数：6

共 14 条

[1] SELECTIVE OXIDATION OF NORMAL-BUTANE TO MALEIC-ANHYDRIDE - A COMPARATIVE-STUDY BETWEEN PROMOTED AND UNPROMOTED VPO CATALYSTS [J].

BEJ, SK ;

RAO, MS .

APPLIED CATALYSIS A-GENERAL, 1992, 83 (02) :149-163

[2]

BIBIN VN, 1968, KINET KATAL, V9, P618

[3]

BIELANSKI A, 1909, OXYGEN CATALYSIS, P103

[4]

Boreskov G. K., 1966, KINET KATAL, V7, P144

[5]

CHADWICK D, 1983, PREPARATION CATALYST, V3, P323

[6]

CHUDINOVA NN, 1975, COMMUN AKAD NAUK USS, V11, P1662

[7]

DELARCO M, 1989, MATER CHEM PHYS, V23, P51

[8]

DENTE M, 1964, CHIM IND-MILAN, V46, P326

[9] HIGH-PERFORMANCE OF IRON(III) PHOSPHATE FOR SELECTIVE OXIDATION OF METHANOL [J].

KLISSURSKI, D ;

RIVES, V ;

ABADZHJIEVA, N ;

PESHEVA, Y ;

POMONIS, P ;

SDOUKOS, T ;

PETRAKIS, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (21) :1606-1607

[10] IRON-CHROMIUM-MOLYBDENUM OXIDE CATALYSTS FOR METHANOL OXIDATION [J].

KLISSURSKI, D ;

RIVES, V ;

PESHEVA, Y ;

MITOV, I ;

ABADZHJIEVA, N .

CATALYSIS LETTERS, 1993, 18 (03) :265-271

← 1 2 →