REGIOCHEMICAL SYNTHESIS OF STRAIGHT CHAIN ACIDS BY THE PALLADIUM(II) CATALYZED HYDROCARBOXYLATION OF OLEFINS WITH OXALIC-ACID

被引：22

作者：

ELALI, B ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,OTTAWA CARLETON CHEM INST,DEPT CHEM,OTTAWA K1N 6N5,ONTARIO,CANADA

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 80卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

CARBON MONOXIDE; CARBOXYLIC ACIDS; OLEFINS; OXALIC ACID; PALLADIUM; PHOSPHINES;

D O I：

10.1016/0304-5102(93)85010-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Olefins react with carbon monoxide and oxalic acid, catalyzed by palladium acetate in the presence of 1,4-bis(diphenylphosphino)butane, to give linear carboxylic acids regioselectively or regiospecifically. This process shows excellent functional group tolerance.

引用

页码：377 / 381

页数：5

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