AUTOXIDATIONS OF EARLY TRANSITION METALLOCENES .1. BIS(ETA-5-PENTAMETHYLCYCLOPENTADIENYL)ZIRCONIUM(IV) DIALKYLS

被引：11

作者：

ATKINSON, JM ^{[1
]}

BRINDLEY, PB ^{[1
]}

机构：

[1] KINGSTON POLYTECH,PENRHYN RD,KINGSTON THAMES KT1 2EE,SURREY,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 411卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)86012-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Results of a study of the autoxidation of bis(eta-5-pentamethylcyclopentadienyl)zirconium alkyls of the general formulae Cp*2ZrR.X (where R = Me, CH2Ph; X = R, Cl) and that of the mixed cyclopentadienyl Cp*CpZr(CH2Ph)2 are described. Rates of initiation and oxidation are compared with those for bis(eta-5-cyclopentadienyl)zirconocenes.

引用

页码：131 / 137

页数：7

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