CHEMICAL-PROPERTIES OF BETA-TRIKETONES - REEXAMINATION OF ALBIZATIS TANDEM ALDOL PROCESS

被引：8

作者：

ARIMOTO, H ^{[1
]}

OHBA, S ^{[1
]}

NISHIYAMA, S ^{[1
]}

YAMAMURA, S ^{[1
]}

机构：

[1] KEIO UNIV,FAC SCI & TECHNOL,DEPT CHEM,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 26期

关键词：

D O I：

10.1016/S0040-4039(00)60735-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The structural revision of the product of the tandem aldol - Swern oxidation process to beta-triketones is reported. Further oxidation of products leading to the corresponding diketones (ex. 4, 5) was observed. The properties of the beta-triketone are also described.

引用

收藏

页码：4581 / 4584

页数：4

相关论文

共 8 条

[1] MILD CONDITIONS FOR CYCLIZATION OF BETA-TRIKETIDES TO THE CORRESPONDING GAMMA-PYRONES CARRYING ADJACENT CHIRAL CENTERS TOWARD BIOMIMETIC SYNTHESIS OF FULLY SUBSTITUTED GAMMA-PYRONE-CONTAINING NATURAL-PRODUCTS [J].

ARIMOTO, H ;

NISHIYAMA, S ;

YAMAMURA, S .

TETRAHEDRON LETTERS, 1990, 31 (39) :5619-5620

[2] SYNTHETIC STUDIES ON FULLY SUBSTITUTED GAMMA-PYRONE-CONTAINING NATURAL-PRODUCTS - SYNTHESIS OF GAMMA-PYRONE DERIVATIVES OBTAINED BY DECOMPOSITION OF PERONIATRIOLS [J].

ARIMOTO, H ;

NISHIYAMA, S ;

YAMAMURA, S .

TETRAHEDRON LETTERS, 1990, 31 (38) :5491-5494

[3] SYNTHETIC STUDIES ON FULLY SUBSTITUTED GAMMA-PYRONE-CONTAINING NATURAL-PRODUCTS - THE ABSOLUTE-CONFIGURATIONS OF ILIKONAPYRONE AND PERONIATRIOL-I AND PERONIATRIOL-II [J].

ARIMOTO, H ;

CHENG, JF ;

NISHIYAMA, S ;

YAMAMURA, S .

TETRAHEDRON LETTERS, 1993, 34 (36) :5781-5784

[4] STEREOSELECTIVE SYNTHESIS OF ALCOHOLS .9. ABSOLUTE-CONFIGURATION OF STEGOBINONE [J].

HOFFMANN, RW ;

LADNER, W ;

STEINBACH, K ;

MASSA, W ;

SCHMIDT, R ;

SNATZKE, G .

CHEMISCHE BERICHTE-RECUEIL, 1981, 114 (08) :2786-2801

[5] PHEROMONE SYNTHESIS .38. SYNTHESIS OF (2S, 3R, 7RS)-STEGOBINONE [2,3-DIHYDRO-2,3,5-TRIMETHYL-6-(1-METHYL-2-OXOBUTYL)-4H-PYRAN-4-ONE] AND ITS (2R, 3S, 7RS)-ISOMER - THE PHEROMONE OF THE DRUGSTORE BEETLE [J].

MORI, K ;

EBATA, T ;

SAKAKIBARA, M .

TETRAHEDRON, 1981, 37 (04) :709-713

[6]

PRATT NE, 1991, SYNLETT, P361

[7] PREPARATION OF 1,3-DIKETONES AND OF NITRO-DIKETONES BY (1-1)-ACYLATION OF LITHIUM ENOLATES WITH ACYL CHLORIDES [J].

SEEBACH, D ;

WELLER, T ;

PROTSCHUK, G ;

BECK, AK ;

HOEKSTRA, MS .

HELVETICA CHIMICA ACTA, 1981, 64 (03) :716-735

[8] MULTIPLE EQUILIBRATION STRATEGIES IN SYNTHESIS - STEREOCONTROLLED SYNTHESIS OF POLYPROPIONATE FRAGMENTS [J].

ZHAO, YB ;

PRATT, NE ;

HEEG, MJ ;

ALBIZATI, KF .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (06) :1300-1301