REACTIONS OF THEOXYLBORANE WITH (PHOSPHINE)RHODIUM HYDRIDE, ALKYL, AND ALLYL COMPLEXES

被引：47

作者：

BAKER, RT ^{[1
]}

OVENALL, DW ^{[1
]}

HARLOW, RL ^{[1
]}

WESTCOTT, SA ^{[1
]}

TAYLOR, NJ ^{[1
]}

MARDER, TB ^{[1
]}

机构：

[1] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 12期

关键词：

D O I：

10.1021/om00162a011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Differences in the reactivity of saturated and unsaturated chelating bis(phosphine)rhodium complexes with thexylborane are described. Reaction of [(Prʹ2PCH2)2]Rh(η-2-Me-allyl) with thexylborane leads to B‒C bond formation at both allyl termini. © 1990, American Chemical Society. All rights reserved.

引用

页码：3028 / 3030

页数：3

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