MOLECULAR STRUCTURE OF BOROXINE, H3B3O3, DETERMINED BY ELECTRON DIFFRACTION

被引：46

作者：

CHANG, CH

PORTER, RF

BAUER, SH

机构：

[1] Department of Chemistry, Cornell University, Ithaca

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 08期

关键词：

D O I：

10.1021/ic50078a024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of H3B3O3 in the gas phase has been determined by electron diffraction, using digitized microdensitometric data. The heavy atoms are arranged in a planar six-membered ring (D3h). Several nonplanar structures were considered and limits were set on the magnitude of out-of-plane distortion for the average conformation. The bond lengths are B-H = 1.192 ± 0.017 and B-0 = 1.3758 ± 0.0021 Å. The bond angles are 120 ± 0.64°. © 1969, American Chemical Society. All rights reserved.

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页码：1689 / &

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