CHEMICAL APPLICATIONS OF TOPOLOGY AND GROUP THEORY .I. COORDINATION POLYHEDRA

被引：87

作者：

KING, RB

机构：

[1] Department of Chemistry, University of Georgia, Athens

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 26期

关键词：

D O I：

10.1021/ja01054a001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Possible polyhedra for coordination numbers four through nine, inclusive, are generated by considering maximum symmetry polyhedra with numbers of vertices (v), edges (e), and faces (f) satisfying the relationships e + 2 = v + f (Euler's relationship), 2e ≥ 3f, 3v ≤ 2e, and 4 ≤ v ≤ 9. The polyhedra corresponding to the various possible sp3dn hybrids are next examined. Polyhedra with minimum flexibilities, maximum symmetries, and maximum numbers of faces are favored in actual complexes. © 1969, American Chemical Society. All rights reserved.

引用

页码：7211 / &

共 26 条

[1]

ABRAHAMS SC, 1964, INORG CHEM, V3, P559

[2] THE CRYSTAL STRUCTURE OF ZRO2 AND HFO2 [J].