SELECTIVE ALKYLATIONS OF 1,4/3,6-DIANHYDRO-D-GLUCITOL (ISOSORBIDE)

被引：77

作者：

ABENHAIM, D

LOUPY, A

MUNNIER, L

TAMION, R

MARSAIS, F

QUEGUINER, G

机构：

[1] UNIV PARIS 11,ICMO,REACT SELECT SUPPORTS LAB,CNRS,UA 478,F-91405 ORSAY,FRANCE

[2] INSA,IRCOF,CNRS,URA 1429,F-76131 MONT ST AIGNAN,FRANCE

来源：

CARBOHYDRATE RESEARCH | 1994年 / 261卷 / 02期

关键词：

D O I：

10.1016/0008-6215(94)84022-9

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Each of the two hydroxyl groups of isosorbide can be alkylated selectively, either by direct alkylation with benzyl chloride or allyl bromide according to the reaction conditions, or by a three-step procedure involving selective monoacetylation, alkylation with four different reagents, and finally deacetylation. Monobutyl and monomethyl derivatives from isosorbide are also described.

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页码：255 / 266

页数：12

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