NEW EXPERIMENTAL SETUP FOR WETTABILITY CHARACTERIZATION UNDER MONITORED OXYGEN ACTIVITY .2. WETTABILITY OF SAPPHIRE BY SILVER OXYGEN MELTS

被引：86

作者：

CHATAIN, D ^{[1
]}

CHABERT, F ^{[1
]}

GHETTA, V ^{[1
]}

FOULETIER, J ^{[1
]}

机构：

[1] ENSEEG,INPG,ION ELECTROCHIM SOLIDE LAB,F-38402 ST MARTIN DHERES,FRANCE

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1994年 / 77卷 / 01期

关键词：

D O I：

10.1111/j.1151-2916.1994.tb06977.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Wetting of silver on sapphire and surface tension of silver are both determined as a function of oxygen activity in a range corresponding to oxygen content in silver varying from 10(-12) to 10(-2). The contact angle is shown to decrease at high oxygen activity when simultaneous decreases in surface tension of silver and interfacial energy between silver and alumina occur. This double oxygen adsorption is thermodynamically analyzed and some relevant parameters inducing oxygen segregation at the silver interfaces are proposed.

引用

页码：197 / 201

页数：5

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