CALCULATION METHOD OF LATTICE ENERGY ON COMPLEX-CRYSTALS

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作者
GAO, FM
ZHANG, SY
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O6 [化学];
学科分类号
0703 ;
摘要
In this paper, based on the consideration of covalent behavior of adjacent ions in crystals, a calculation formula of lattice energy was proposed. In which, the concept of ionic effective valence and the empirical formula covalent energy were introduced, so that the calculation of littice energy can be extended from binary ionic crystals to polar covalent crystals and complex crystals. The calculation results are in agreement with the experimental observations.
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页码:320 / 324
页数:5
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