VANADIUM REDOX REACTIONS AND CARBON ELECTRODES FOR VANADIUM REDOX FLOW BATTERY

被引：175
|
作者：
KANEKO, H
NOZAKI, K
WADA, Y
AOKI, T
NEGISHI, A
KAMIMOTO, M
机构：
[1] EBARA RES CO LTD,FUJISAWA,KANAGAWA 251,JAPAN
[2] ISOGO TECH HIGH SCH,YOKOHAMA 943,JAPAN
来源：
ELECTROCHIMICA ACTA | 1991年 / 36卷 / 07期
关键词：
V-V REDOX FLOW BATTERY; ELECTRODE REACTION RATE CONSTANTS; VANADIUM IONS; CYCLIC VOLTAMMETRY; CARBON CLOTH ELECTRODE; CHARGE DISCHARGE EXPERIMENT OF V-V-H2SO4 SYSTEM; GRAPHITE-REINFORCEMENT CARBON ELECTRODE;
D O I：
10.1016/0013-4686(91)85108-J
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The redox reactions of vanadium ions in sulfuric acid, which are used for anolyte and catholyte in a redox flow battery, have been investigated on a GRC (graphite reinforcement carbon) electrode. Two types of carbon fiber electrodes (GF-20 and BW-309) have been evaluated for the battery electrode. As a result, the BW-309 was found to be best. Cyclic voltammetry has been used to estimate electrode reaction rate constants of the ions on a GRC electrode and two carbon fiber electrodes and to determine the suitable concentration of sulfuric acid for vanadium redox reactions in the battery. A charge-discharge experiment of V-V system in 2 M (mol dm-3) sulfuric acid solution has also been carried out on the carbon cloth (BW-309) electrode.
引用
收藏
页码：1191 / 1196
页数：6
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