T-for-H substitution in methane: A hot-atom reaction with walden inversion?

被引：32

作者：

Bunker, Don L. ^{[1
]}

Pattengill, Merle ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92717 USA

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 4卷 / 05期

关键词：

D O I：

10.1016/0009-2614(69)80195-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Trajectory studies of the hot-atom reactions of tritium with methane have been made in which all six atoms Were tracked. Abstraction of H by T is a direct reaction. as expected. but T-for-H substitution is a concerted process involving: at least four atoms. There are indications that it may proceed with inversion of the methane structure.

引用

页码：315 / 316

页数：2

共 7 条

[1] MONTE CARLO CALCULATIONS .2. REACTIONS OF ALKALI ATOMS WITH METHYL IODIDE [J].