LIFETIMES AND PREDISSOCIATION IN ALH(ALD) A1II

被引：48
作者：
BALTAYAN, P
NEDELEC, O
机构：
[1] Laboratoire de Spectrométrie Physique, Université Scientifique et Médicale de Grenoble, 38041 Grenoble Cedex
来源：
JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 05期
关键词：
D O I：
10.1063/1.437749
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Radiative lifetimes of AIH(AID) A 1Π have been measured in a hollow cathode discharge by dye laser excitation, in ns: AIH{ v′ = 1: 83 ± 6v′ = 0: 66± 4 AID{v′ = 1: 74 ± 5v′ = 0: 64± 5 Predissociated rotational levels lifetimes are given and used to precise the shape of the hill of the A 1Π potential energy curve crossed by tunnel effect. The AIH dissociation energies are found: for A 1Π, De(eV) = 0.24±0.01 and for X 1Σ+, De(eV) = 3.16±0.01. The normal levels lifetimes variation with v′ is attributed to a configuration mixing in A 1Π. © 1979 American Institute of Physics.
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页码：2399 / 2403
页数：5
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