Acetonyltriphenylphosphonium nitrate

被引：4

作者：

Diop, Tidiane ^{[1
]}

Diop, Libasse ^{[1
]}

Kucerakova, Monika ^{[2
]}

Dusek, Michal ^{[2
]}

机构：

[1] Univ Cheikh Anta Diop, Fac Sci & Tech, Dept Chim, Lab Chim Minerale & Analyt, Dakar, Senegal

[2] Inst Phys ASCR, Prague 18221 8, Czech Republic

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

data-to-parameter ratio = 13.6; mean σ(C-C) = 0.002 Å; R factor = 0.033; single-crystal X-ray study; T = 120 K; wR factor = 0.094;

D O I：

10.1107/S1600536813002110

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Crystals of the title salt, C21H20OP+center dot NO3-, are composed of acetonyltriphenylphosphonium cations and nitrate anions that mainly interact through electrostatic forces. The P atom in the cation has a slightly distorted tetrahedral environment, with C - P - C angles ranging from 104.79 (7) to 112.59 (6)degrees. The sum of O - N - O angles of the nitrate anion is 359.99 degrees, reflecting its trigonal-planar character. C-H center dot center dot center dot O hydrogen bonds help to consolidate the crystal packing.

引用

页码：O303 / +

页数：8

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