PICOSECOND TIME-DEPENDENT STOKES SHIFT STUDIES OF FLUOROPROBE IN LIQUID SOLUTION

被引：31
|
作者：
MIDDELHOEK, ER [1 ]
VANDERMEULEN, P [1 ]
VERHOEVEN, JW [1 ]
GLASBEEK, M [1 ]
机构：
[1] UNIV AMSTERDAM,ORGAN CHEM LAB,1018 WS AMSTERDAM,NETHERLANDS
来源：
CHEMICAL PHYSICS | 1995年 / 198卷 / 03期
关键词：
D O I：
10.1016/0301-0104(95)00219-E
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report on a picosecond spectroscopic study of the dynamical Stokes shift of fluoroprobe in the lowest excited state in the solvents diethylether and ethylacetate. Time-resolved emission spectra with a time-resolution of approximately 10 ps are presented. The spectra reflect dynamical Stokes shifts of a few thousand wave numbers within 10-100 ps after the pulsed laser excitation. The time-dependent shifts are representative of the solvation dynamics of fluoroprobe in diethylether and ethylacetate.
引用
收藏
页码：373 / 380
页数：8
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