SELF-ASSEMBLY OF MAIN-CHAIN LIQUID-CRYSTALLINE POLYMERS VIA HETEROMERIC HYDROGEN-BONDING

被引：106

作者：

ALEXANDER, C ^{[1
]}

JARIWALA, CP ^{[1
]}

LEE, CM ^{[1
]}

GRIFFIN, AC ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,MELVILLE LAB POLYMER SYNTH,PEMBROKE ST,CAMBRIDGE CB2 3RA,ENGLAND

来源：

MACROMOLECULAR SYMPOSIA | 1994年 / 77卷

关键词：

D O I：

10.1002/masy.19940770130

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Complexation between pyridines and carboxylic acids is driven by hydrogen bonding. This simple, single hydrogen bond is shown to be capable of serving concomitantly as both the agent of liquid crystallinity and as the coupling bond generating an extended linear chain structure. Three such complexes made from an aromatic diacid and three structurally different bis pyridyls were prepared. In each case the association complex self-assembles into an organized liquid crystalline phase. Discussion of this complexation as a step-growth polymerization process is presented along with an examination of the suitability of various methods for characterizing these materials.

引用

页码：283 / 294

页数：12

共 30 条

[1] AN HEXAGONAL COLUMNAR MESOPHASE IN HALF-DISK-SHAPED THALLIUM (I) COMPLEXES [J].

BARBERA, J ;

CATIVIELA, C ;

SERRANO, JL ;

ZURBANO, MM .

ADVANCED MATERIALS, 1991, 3 (12) :602-605

[2] Mesomorphism and polymorphism of some p-alkoxybenzoic and p-alkoxycinnamic acids [J].

Bennett, GM ;

Jones, B .

JOURNAL OF THE CHEMICAL SOCIETY, 1939, :420-425

[3]

BLADON P, UNPUB

[4] MACROSCOPIC EXPRESSION OF MOLECULAR RECOGNITION - SUPRAMOLECULAR LIQUID-CRYSTALLINE PHASES INDUCED BY ASSOCIATION OF COMPLEMENTARY HETEROCYCLIC COMPONENTS [J].

BRIENNE, MJ ;

GABARD, J ;

LEHN, JM ;

STIBOR, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (24) :1868-1870

[5]

FREITAS LD, 1988, COLLOID POLYM SCI, V266, P1095

[6] LIQUID-CRYSTAL PHASES EXHIBITED BY SOME MONOSACCHARIDES [J].

GOODBY, JW .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1984, 110 (1-4) :205-219

[7] MESOGENIC POLYMERS .3. THERMAL-PROPERTIES AND SYNTHESIS OF 3 HOMOLOGOUS SERIES OF THERMOTROPIC LIQUID-CRYSTALLINE BACKBONE POLYESTERS [J].

GRIFFIN, AC ;

HAVENS, SJ .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1981, 19 (06) :951-969

[8] COOPERATIVE STRUCTURE FORMATION BY COMBINATION OF COVALENT AND ASSOCIATION CHAIN POLYMERS .6. MOLECULAR-ORIGIN OF SUPRAMOLECULAR SELF-ASSEMBLING IN STATISTICAL COPOLYMERS [J].

HILGER, C ;

DRAGER, M ;

STADLER, R .

MACROMOLECULES, 1992, 25 (09) :2498-2501

[9] COOPERATIVE STRUCTURE FORMATION BY COMBINATION OF COVALENT AND ASSOCIATION CHAIN POLYMERS .4. DESIGNING FUNCTIONAL-GROUPS FOR SUPRAMOLECULAR STRUCTURE FORMATION [J].

HILGER, C ;

STADLER, R .

POLYMER, 1991, 32 (17) :3244-3249

[10]

HILGER C, 1991, MAKROMOL CHEM, V192, P805

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