POLYMER COMPLEXES .18. POLYCHELATES FROM POLY(5-VINYL SALICYLIDENE HYDRAZINE-S-BENZYL DITHIOCARBAZATE) WITH SOME TRANSITION-METAL SALTS

被引：26

作者：

ELSONBATI, AZ

机构：

[1] Chemistry Department, Faculty of Science, Mansoura University, Demiatta

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1991年 / 21卷 / 02期

关键词：

D O I：

10.1080/15533179108020176

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes derived from polymeric 5-vinyl salicylidene hydrazine-S-benzyl dithiocarbazate (VSH) with CuCl2, CoCl2, NiCl2, CdCl2 and uranyl acetate were prepared and characterized by elemental analysis, spectroscopic and magnetic measurements. The functional groups of PVSH from 1:1 complexes with CuCl2, NiCl2 and CdCl2 and 1:2 complexes with CoCl2 and uranyl acetate. The stereochemistry of the polymer complexes have been studied with the help of magnetic and spectroscopic measurements.

引用

页码：203 / 216

页数：14

共 12 条

[11] VINYLIDENE TRANSITION-METAL COMPLEXES .18. (ARENE)OSMIUM COMPLEXES CONTAINING ALKYNYL, VINYL, VINYLIDENE, AND THIO- AND SELENOKETENE UNITS AS LIGANDS - A SERIES OF ORGANOMETALLIC COMPOUNDS BUILT UP FROM 1-ALKYNES
WERNER, H
WEINAND, R
KNAUP, W
PETERS, K
VONSCHNERING, HG
ORGANOMETALLICS, 1991, 10 (12) : 3967 - 3977
[12] Coordination chemistry and bioactivity of some metal complexes containing two isomeric bidentate NS Schiff bases derived from S-benzyldithiocarbazate and the X-ray crystal structures of S-benzyl-β-N-(5-methyl-2-furylmethylene)dithiocarbazate and bis[S-benzyl-β-N-(2-furylmethylketone)dithiocarbazato]cadmium(II)
Tarafder, MTH
Khoo, TJ
Crouse, KA
Ali, AM
Yamin, BM
Fun, HK
POLYHEDRON, 2002, 21 (27-28) : 2691 - 2698

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