POLYMER COMPLEXES .18. POLYCHELATES FROM POLY(5-VINYL SALICYLIDENE HYDRAZINE-S-BENZYL DITHIOCARBAZATE) WITH SOME TRANSITION-METAL SALTS

被引:26
|
作者
ELSONBATI, AZ
机构
[1] Chemistry Department, Faculty of Science, Mansoura University, Demiatta
关键词
D O I
10.1080/15533179108020176
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Complexes derived from polymeric 5-vinyl salicylidene hydrazine-S-benzyl dithiocarbazate (VSH) with CuCl2, CoCl2, NiCl2, CdCl2 and uranyl acetate were prepared and characterized by elemental analysis, spectroscopic and magnetic measurements. The functional groups of PVSH from 1:1 complexes with CuCl2, NiCl2 and CdCl2 and 1:2 complexes with CoCl2 and uranyl acetate. The stereochemistry of the polymer complexes have been studied with the help of magnetic and spectroscopic measurements.
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页码:203 / 216
页数:14
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