REGIOSELECTIVITY OF THE AMINATION OF SOME 3-NITROPYRIDINES BY LIQUID-AMMONIA POTASSIUM-PERMANGANATE

被引：0
|
作者：
WOZNIAK, M
BARANSKI, A
SZPAKIEWICZ, B
机构：
来源：
LIEBIGS ANNALEN DER CHEMIE | 1991年 / 09期
关键词：
AMINATION; NITROPYRIDINES; REACTIVITY INDEXES; CALCULATIONS; MNDO;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
3-Nitropyridine and some of its derivatives are aminated in a liquid ammonia solution of potassium permanganate to the corresponding 2- and (or) 4- and (or) 6-amino compounds. Quantumchemical calculations for a few 3-nitropyridines suggest that the experimentally observed regioselectivity of the amination is controlled by Coulombic interaction.
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页码：875 / 878
页数：4
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