ELECTROCONDUCTIVE ORGANOGEL .2. APPEARANCE AND NATURE OF CURRENT OSCILLATION UNDER ELECTRIC-FIELD

被引：15

作者：

MIYANO, M ^{[1
]}

OSADA, Y ^{[1
]}

机构：

[1] IBARAKI UNIV,DEPT CHEM,MITO,IBARAKI 310,JAPAN

来源：

MACROMOLECULES | 1991年 / 24卷 / 17期

关键词：

D O I：

10.1021/ma00017a005

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An artificial oscillation system consisting of an acceptor-doped electroconductive organogel, to which a constant electric potential was applied, is described. This organogel is made of cross-linked polymer donor subsequently doped with low molecular acceptor and swollen in N,N-dimethylformamide. It was found that repetitive oscillations occurred in these gels above a certain threshold potential in organic solvent. The nature of the oscillation was associated with the degree of cross-linking, the doping ratio of acceptor molecule, and temperature; an increase of these parameters enhanced both the amplitude and frequency of the oscillation. A possible mechanism of the oscillation is also briefly described.

引用

页码：4755 / 4761

页数：7

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