THE CRYSTAL-STRUCTURES OF [CU2CL2(AA-CENTER-DOT-H+)(2)](NO3)(2) AND [AA-CENTER-DOT-H+]PICR(-) (AA-CENTER-DOT-H+=ALLYLAMMONIUM PICR(-)=PICRAT)

被引：6

作者：

OLIJNYK, VV

MYSKIV, MG

机构：

[1] L'viv, 290005

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 10期

关键词：

BIS(DIALLYLAMMONIUM)DICHLOROCOPPER(I) NITRATE; ALLYLAMMONIUM PICRATE; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19956211022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By an alternating current electro synthesis the crystalline pi-complex [Cu2Cl2(AA . H+)(2)](NO3)(2) has been obtained from CuCl2 . 2H(2)O, allylamine (AA), and HNO3 in ethanolic solution. X-ray structure analysis revealed that the compound crystallized in the monoclinic system, space group P2(1)/a, a = 7.229(3), b = 7.824(3), c = 26.098(6) Angstrom, gamma = 94.46(5)degrees, Z = 4, R = 0.025 for 2023 reflections. The crystal structure is built up of CunCln chains which are connected by pi-bonding bidentate AA . H+... ON(O)O ... H+. AA units. For comparision with the above complex the structure of[AA . H+] Picr(-) (Picr(-) = picrate anion) is also reported.

引用

页码：1741 / 1745

页数：5